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One of the two is substantially more stable than the other. Which is more stable Explain. (Rasanen, M.; Aspiala, A.; Homanen, L.; Murto, J., J. Mol. Struct., 1982, 96, 81.) Answer to 5(b). The orbitals and orbital energies of generic NH2 and OH groups are shown side by side in Figure B10.1. Conformations a and b exhibit hydrogen-bonding interactions a and b, respectively. Interaction b is favored by the smaller energy gap and additionally by increased polarization of both nN and sOH orbitals. 6. The bond dissociation energy (BDE) and acidity constant pKa of cubane (Cub H) have been determined experimentally by Eaton and co-workers (Hare, M.; Emrick, T.; Eaton, P. E.; Kass, S. R., J. Am. Chem. Soc., 1997, 119, 237 238). The BDE is unusually high for a tertiary C H bond, 427 kJ/mol, about 25 kJ/mol higher than in isobutane. The C H bond is also quite acidic, comparable to the acidity of the N H bond in ammonia, pKa 36, indicating an unusual stability for the anion

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100 Cumulative distribution function (%) 90 80 70 60 50 40 30 20 10 0 -20 -10 0 10 20 G factor (dB) 30 40

Figure A-37: These are examples of applying nine patterns from the Displacement Maps folder with the Displace filter at 10 percent horizontally and vertically.

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I love the Net If I can t check my email, I become as cranky as someone who hasn t had her morning coffee If I can t get web access, my hands start shaking and I feel dizzy The Net is a great place to get information (and misinformation), to talk to people (and be ranted at by kooks), to get things done (or mess them up), and most of all, to buy books However, remember that the Net was started as a research tool ARPAnet was created by the Department of Defense, but they didn t think to apply their own standards of security to it As things stand now, it is not possible for me to authenticate a site a website, a server, a chatroom, whatever on the Net.

The IRS is looking at online auctions in part from the standpoint as to how they are conducted. Some tax-exempt organizations conduct their own; others use outside service providers. Some online auction Web sites provide services for exempt organizations only; some sites and search engines also operate auctions for individuals and for-profit organizations. The advantages to utilization of an outside auction service provider include provision of a larger auction audience than might be available if the exempt organization conducted it itself and avoidance of credit card fraud problems. Yet, as the IRS delicately phrased the matter, entering into an agreement with an outside service provider might have tax implications. One of the factors considered by the IRS is the degree of control (if any) the taxexempt organization will exercise over the marketing and conduct of the auction. The IRS wants the event to be sufficiently segregated from other, particularly noncharitable auction activities (whatever that may mean) and the exempt organization to retain primary responsibility for publicity and marketing. Otherwise, the agency may be more likely to view income from such auction activities as income from classified advertising rather than as income derived from the conduct of a fundraising event. Also, the IRS has characterized these service providers as essentially professional fundraisers. It is not clear what the point of that analogy is, but nonetheless the IRS will scrutinize their functions and fees using traditional [private] inurement and private benefit principles. The agency might have mentioned that the intermediate sanctions rules also are applicable in this setting.

4.6.3 Design with a Triangular Patch To achieve dual-polarized radiation of a triangular microstrip antenna with highly decoupled feeding ports and low cross-polarization, the two feed positions for the dual linear polarizations need to be carefully determined. The selection of proper feed positions is described here. Figure 4.81 shows the antenna geometry. The triangular patch is equilateral and has a side length L. The feed position (x1 , y1 ) = (0, y1 ) of port 1 is placed along the centerline (y axis) of the patch for the excitation of the fundamental mode of TM10 , which has a polarization plane along the y z plane in the gure. In order to excite a linearly polarized wave with its polarization plane orthogonal to the y z plane and have good port decoupling, the possible feed position (x2 , y2 ) of port 2 is between points A and B along the null-voltage locus for port 1 excitation. Points A and B are, respectively, the intersections of the null-voltage locus with the loci 1 and 2 , which represent the loci with 50- input impedance for the excitation of a linearly polarized wave with its polarization plane 30 and 30 slanted to the x z plane, respectively. Note that, when high port decoupling is not considered, the optimal feed position should be at point C, the intersection of loci 1

Uniform, 18.75%