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a factor of 10 50. The disadvantage of this method is that most of the mass spectral information for the component is lost. This is not much better than having a gas chromatograph with a ame ionization detector. For, in trace-level work, any component that has an ion with the same mass as the one being scanned and the same retention time will be mistaken for the component of interest. These small peaks are called chemical noise. On the other hand, with a tandem (dual-stage) mass spectrometer system, the chemical noise can be reduced almost to zero, lowering the limit of detection signi cantly. In tandem mass spectrometry (as the name implies), a second mass spectrometry stage is added to the rst. This allows the analyst to select one of the fragment ions from the rst mass spectrum for further fragmentation. Now, we have a mass spectrum of an ion, whereas in single-stage mass spectrometry we have a mass spectrum of a molecule. Recalling the discussion earlier about selected ion monitoring, one can now apply this same principle to tandem mass spectrometry. With this technique, one selects the most abundant fragment ion from the rst mass spectrum for secondstage fragmentation. This is called the parent ion. A mass spectrum is obtained; from this spectrum, one selects the most abundant ion to monitor in the same manner as SIM. This is called the daughter ion. Now, when the sample is chromatographed, only those peaks will show up at the desired retention time that contain the daughter ion originating from the parent ion that was selected from the original mass spectrum. This greatly reduces the signal background or chemical noise. F.1.19 X-Ray Fluorescence (XRF) microsoft word barcode font Get Barcode Software - Microsoft Store
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